Obtaining Kinetic Parameters by Modulated Thermogravimetry

A new technique, called modulated thermogravimetry, is introduced as a tool for obtaining continuous kinetic information for decomposition and volatilization reactions. The approach makes use of an oscillatory temperature program to obtain kinetic parameters during a mass loss. MTGA may be used under quasi-isothermal conditions to observe a single mass loss or may be combined with linear heating rate or Hi-Res controlled rate thermogravimetry to scan from one mass loss region to another. Results obtained are in agreement with those obtained by other kinetic methods.